Ms Okpe said men of the Ogun State Fire Service were at the scene of the crash, with efforts ongoing to put out the fire.
The Lagos Division of the Federal High Court on Monday convicted and jailed three men for illegally dealing in restricted drugs.
According to her, the truck was conveying cows and human beings together.
The cleric also called on the government to tackle insecurity.
The sector commander said that the vehicles of offenders would be impounded.
A falling 40-feet container killed a woman inside her car at the Lagos end of the Lagos-Ibadan Expressway on Friday.
She advised motorists to drive within the stipulated speed limit.
He said the FRSC had met with animal dealers in the Kara area of the Lagos-Ibadan expressway to inform them of the dangers.
Five persons were confirmed dead in an accident on Fidiwo bridge on the Lagos-Ibadan expressway.
Mrs Okpe attributed the fatal crash to reckless driving by the truck drivers.
