The Zamfara Anti-thuggery Committee has begun clamping down on filling stations, markets and other business centres, rejecting the old naira notes.
The Council of State had of Friday advised the CBN to allow the new and old naira notes to co-circulate to ease the pains and sufferings of Nigerians.
Investigation showed that many residents still possessing the old naira notes find it challenging to spend them.
The governor noted that the old currency notes remained legal tender until the final verdict of the Supreme Court on the matter.
The National Union of Road Transport Workers (NURTW) has directed its members to continue to receive the old naira notes until February 10.
On Sunday, CBN governor Godwin Emefiele announced a new deadline of February 10, with an additional seven days grace period for deposits.
The governor urged the federal government to extend the deadline due to unavailability of the new notes for Nigerians.
The Central Bank of Nigeria (CBN) has vowed to sanction commercial banks dispensing old naira notes ahead of the January 31 deadline.
