Mrs Azarnykh was sanctioned on 5 May.
The shipment, the second batch of medical supplies provided to Iran, was transported by rail to the city of Astara.
Mr Putin said Mr Khamenei will be remembered in Russia as an outstanding statesman.
The appeal trial of French far-right leader Marine Le Pen against her conviction in a case involving the alleged misuse of European Union funds is set to begin on Tuesday.
Moscow claimed Ukraine attempted to attack Mr Putin’s Valdai residence in western Russia with 91 drones, all of which it said were shot down.
The White House has yet to confirm the meeting.
Mr Putin repeatedly uses the televised event to portray himself as a caring leader and problem solver. Last year’s show lasted just under four and a half hours.
Russia is not looking to rejoin G7, President Vladimir Putin said during a visit to India on Thursday.
The United States of America initially proposed a 28-point plan aimed at ending the conflict.
If he pushes for a two-state solution and manages to get Vladimir Putin and Volodymyr Zelenskyy to a round table, that might be the medal-worthy deal of our lifetime!
